FUW TRENDS IN SCIENCE & TECHNOLOGY JOURNAL

(A Peer Review Journal)
e–ISSN: 2408–5162; p–ISSN: 2048–5170

FUW TRENDS IN SCIENCE & TECHNOLOGY JOURNAL

REMOVAL OF LEAD AND CADMIUM FROM AQUEOUS SOLUTION USING ACTIVATED CARBONS FROM DESERT DATE AND SHEA NUT SHELLS
Pages: 695-701
Z. Abdullahi, A. I. Ajai* and Y. A. Iyaka


keywords: Adsorption, Balanitesaegyptiaca, heavy metals, kinetic, Vitellariaparadoxa,wastewater

Abstract

Shells of Balanitesaegyptiaca (desert date) and Vitellariaparadoxa (shea nut) activated with 1.00 mol/dm3H2SO4and their blends were investigated for the removal of Pb and Cd from aqueous solution. Effects of operational parameters, such as contact time, pH, initial metal ion concentration and temperature were investigated. The adsorption process was found to be dependent on all the factors investigated. The optimum pH for the removal of Pb was 6, while Cd was found to be 8. Optimum contact time for Pb and Cd was 90 min. Highest removal of Pb and Cd was 70 and 65%, respectively. The adsorptive capacity of all the adsorbent used was in the order AC2>AC4>AC3>AC1. Experimental data tested fitted better into the Freundlich isotherm compared to the Langmuir isotherm. Adsorption kinetic of the process was best described by pseudo-second order model. Thermodynamic investigations showed that the process was spontaneous, feasible, and endothermic and proceed with increasing randomness.

References

Adeogun AI, Ofudje AE, Idowu M & Kareem SO 2011. Equilibrium, kinetics and thermodynamic studies of the bisorption of Mn(II) Ions from aqueous solution by raw and acid – treated corn-cob biomass. Biores., 6(4): 4117 – 4134. Ahamed JA & Begum SA 2012.Adsorption of copper from aqueous solution using low cost adsorbent.Arch. Appl. Sci. Res., 4(3): 1532 – 1539. Ahmed LA 2010. Removal of heavy metal from waste water by date palm tree wastes. Engr. & Tech. J., 28(1): 115-119. Amir HM &Edriss B 2007.Removal of cadmium from industrial effluents by electrocoagulation process using aluminum electrodes.World Appl. Sci. J., 2(1): 34-39. Amuda O, Giwa SA &Bello AI 2007.Removal of heavy metal from industrial waste water using modified activated coconut shell carbon.Biochem.Engin. J., 36: 174–181. Anusha G 2011.Removal of iron from waste water using bael fruit shell as adsorbent.2nd Int. Conf. on Envt. Sci. & Tech., 6: 258-260. Bansal M, Singh D, GargVK& Rose P 2009. Use of agricultural waste for the removal of nickel ions from aqueous solutions: Equilibrium and kinetics studies. World Acad. Sci. Engr. & Tech., 3(3): 03-25. Chaturvedi D &Sahu O 2014.Adsorption of heavy metal ions from wastewater.Glob. J. Envt. Sci. & Tech., 2(3), 020-028. DeosarkarSD 2012. Thermodynamics of adsorption of Pb(II) and Cd(II) metal ions from aqueous solution by PunicagranatumL. Husk. J. Chem. & Pharm. Res., 4(6): 3319-3323. EgilaJN, Jimoh TO, IfunanyaGN&Dayo O 2012.Comparism of adsorption behsaviour of Caryotaruumphiana flower and goat hooves to lead and manganese ions in aqueous solution.Amer. J. Envir. Engin., 2(4): 86-90. El-Batouti M & Ahmed AM 2014. Adsorption kinetic of Nickel(II) onto activated carbon prepared from natural adsorbent rice husk. Int. J. Tech. Enhancement & Emerging Engr. Res., 2(5): 145-148. Ge P & Li F 2011. Kinetics and thermodynamics of heavy metal Cu(II) adsorption on mesoporous silicates. Pol. J. Envit.l Stud., 20(2): 339-344. Giwa AA, Bello IA, Oladipo MA &Adeoye DO 2013. Removal of cadmium from waste water by adsorption using the husk of melon seed.Int. J. Basic & Appl. Sci., 2(1): 110-123. Ghasemi N, Ghasemi M, Mashhadi S &Tarraf MH 2012. Kinetics and isotherms studies for the removal of Ni(II) from aqueous solutions using Rosa canina L. Int. Conf. on Inf., Envt., Energy &Applt., 38: 87-92. HorsfallMJ&Spiff AI 2005. Effects of temperature on the sorption of Pb2+ and Cd2+ from aqueous solution by Caladium bicolor biomass.Elect. J. Biotech.,8(2): 87-96. Ibrahim MB &Jimoh WL 2008. Adsorption studies for the removal of Cr(VI) ion from aqueous solution. Bayero J. Pure & Appl. Sci., 1(1): 99-103. Itodo AU, Abdulrahman FW, Hassan G, Maigandi SA &Itodo HU 2010.Intraparticle diffusion and intraparticulate diffusivities of herbicide on derived activated carbon.Researcher, 2(2): 43-49. Kailas LW 2010.Adsorption of metals onto tea factory waste.Int. J. Res. and Rev. in Appl. Sci., 3(3): 303-322. Kalia K &Flora SJ 2005.Strategies for Safe and Effective Therapeutic Measures for Chronic Arsenic and Lead Poisoning.J. Occup. Health, 47(1): 1-21. Mammatha M, AravindaHB, Puttaiah ET &Manjappa S 2013. Factors and kinetics involved in adsorption of copper from aqueous and waste water onto Pongamiapinnata.Int. J. Innov. Res. Sci. Engin. & Tech., 2(4):105-115. Murithi G, Onindo CO, WambuEW&MuthakiaGK 2014.Removal of cadmium (II) ions from wastewater by adsorption using water hycinth (Eichhorniacrassipes) biomass.Biores., 9(2): 3613-3631. Nassef E 2013.Thermodynamics and kinetic study of using modified clay as an adsorbent for the removal of Zn ions from waste water. J. Am. Sci., 9(9): 35-447. NgahWS W &HanafiahMAK 2008. Removal of heavy metal ions from waste water by chemically modified plant waste as adsorbents. Biores. Tech., 99: 3935-3948. Nitin WI &Sachin VD 2012.State of art of biosorption technique for treatment of heavy metals bearing wastes.Int. J. Adv. Engin. Tech., 3(2): 143-153. PatilSJ, Bhole AG &NatarajanGS 2006. Scavenging of Ni(II) metal ions by adsorption on pac and babhul bark. J. Envt. Sci. &Engin., 48(3): 203-208. Qaiser S, Saleemi AR &Umar M 2009.Biosorption of lead (II) and chromium (VI) on groundnut hull: Equilibrium, kinetics and thermodynamics study. Elect. J. Biotech., 2(4): 346-352. Rafique U &Nazir S 2013. Heavy metal removal from waste water using environmental friendly bio-materials: A Cost effective and eco-friendly technique. Int. J. Chem. &Envt.Engin., 4(2), 90-99. Renge VC, KhedkarSV&PandeSV 2012.Removal of heavy metals from waste water using low cost adsorbents.Scient. Rev. & Chem. Comm., 2(4): 580-584. Saifuddin MN &Kumaran P 2005. Removal of heavy metal from industrial wastewater using chitosan coated oil palm shell charcoal.Elect. J. Biotech., 4(6): 115-122. Sarin V &Pant KK 2006. Removal of chromium from industrial waste by using eucalyptus bark.Bioresc. Tech., 97: 15–20. Shelke RS, Madje BR, Bharad JV &Ubale MB 2009. Adsorption of nickel(II), copper(II) and iron(III) from aqueous solution using ashoka leaf powder. Int. J. Chem. Tech. Res., 1(4): 1318-1325. Thakur LS&Parmar M 2013.Adsorption of heavy metal from synthetic waste water by tea waste adsorbent.Int. J. Chem. & Phys. Sci., 2(6):6-19. Tuama AH &Mohammed AA 2014. Removal of heavy metal ions from aqueous solutions using tobacco leaves as a sorbent. Euro. J. Appl. Engin. &Scient. Res., 3(2): 19-32. Wahi R &Senghie H 2011. The Use of Micro Wave Derived Activated Carbon for Removal of Heavy Metal in Aqueous Solution. J. Sci. & Tech., 8(1): 45-56.

Highlights